最后终于找到了正确的修改方法:

1）查看当前的编码：show variables like 'character%';

+--------------------------+----------------------------+
| Variable_name | Value |
+--------------------------+----------------------------+
| character_set_client | latin1 |
| character_set_connection | utf8 |
| character_set_database | latin1 |
| character_set_filesystem | binary |
| character_set_results | utf8 |
| character_set_server | latin1 |
| character_set_system | utf8 |
| character_sets_dir | /usr/share/mysql/charsets/ |
+--------------------------+----------------------------+

2)修改my.cnf，在[client]下添加default-character-set=utf8

3）在[mysqld]下添加

init_connect='SET collation_connection = utf8_unicode_ci'
init_connect='SET NAMES utf8'
character-set-server=utf8
collation-server=utf8_unicode_ci
skip-character-set-client-handshake

4)重新启动,ok!

修改后:

mysql> show variables like 'character%';
+--------------------------+----------------------------+
| Variable_name | Value |
+--------------------------+----------------------------+
| character_set_client | utf8 |
| character_set_connection | utf8 |
| character_set_database | utf8 |
| character_set_filesystem | binary |
| character_set_results | utf8 |
| character_set_server | utf8 |
| character_set_system | utf8 |
| character_sets_dir | /usr/share/mysql/charsets/ |
+--------------------------+----------------------------+